Naoya Shirakawa
A male student at Seika High School who dislikes Misaki because of her forceful methods to make the male students acceptable. He and his friends discover that she works at a maid café early on in the story, but after she is defended by Usui, they quickly become her biggest fans and begin to frequent the café where she works often. His nickname is “Shiroyan.”

Ikuto Sarashina
A member of the “idiot trio” who became big fans of Misaki not long after learning she was a maid at a maid café. A closet otaku, he is actually good at drawing manga illustrations and enjoys writing. His friends call him “Ikkun.”

Ryuunosuke Kurosaki
The third member of the “idiot trio” who frequent Café Latte and are big fans of Misaki. After learning her secret, they choose not to tell everyone at school because Usui came to her defense. He is nicknamed “Kurotatsu.”

Shouichirou Yukimura
The Vice President of the Student Council, he is helpful towards Misaki and enjoys office routine. He and the rest of the Student Council are quite fearful of Misaki, but respect her because the changes she has brought to improve the school. Yukimura is competent, serious, and capable of doing most administrative work, but is physically weak, especially in comparison to Misaki and Usui. He has a seven-year-old sister named Rui. His first kiss was stolen by Usui.

Sakura Hanazono
One of the few female students at Seika High, Sakura is friendly and cheerful and relies on Misaki, seeing her as an older sister. She is actually quite popular amongst the boys, but frequently rejects their confessions; in particular, she’s rejected ex-rugby captain Masaru Gouda one hundred times. According to Shizuko, Sakura falls in love without carefully considering what the person is really like.

Shizuko Kaga
One of Misaki and Sakura’s friends, a calm and collected girl who often spends lunchtime with them. Shizuko is a member of the flower arranging club and is good at math, but isn’t very good at physical activities. She has an older brother in university and a younger sister in junior high school; according to Sakura, the three of them look very alike.

Soutarou Kanou
A withdrawn male student who is against Misaki as the Student Council President because she is a girl. Not wishing for the female population to increase, Kanou tries to hypnotize Misaki, Usui, and the Student Council in order to ruin Misaki’s reputation. When his attempt fails, it is revealed that his gynophobic attitude comes from his mother abandoning his family when he was young and his father warning him to be wary of women. For failing to hypnotize Misaki, she punishes him by forcing him to constantly work with his female classmates during an open house for the school so that he can over his fear of women. He begins to regard her in a friendlier manner afterward.

Hinata Shintani
A childhood friend of Misaki who came to Seika High in search of his first love – Misaki. When they were children, he was an overweight boy who Misaki saved when he fell from a tree. He fell in love with her, but soon moved away to live with his grandfather in the countryside when his parents died. When he returns, his appearance changed considerably from losing so much weight (supposedly from eating nothing but vegetables), though he remains a glutton. He is rather gullible and has a one-sided rivalry against Usui to win Misaki’s affection.

Café Latte

Satsuki
The manager of Café Latte and Misaki’s boss, a 30 year old woman who has a tendency to voice out her fantasies. She is a cheerful woman who enjoys her job because it allows her to make others happier. She is very understanding of Misaki’s circumstances, knowing that Misaki does not particularly enjoy working at a maid café, and is perceptive of other people’s feelings. Satsuki also ends up hiring Usui as a part-time cook, much to Misaki’s chagrin.

Honoka
An employee at Café Latte. Despite her pleasant demeanor, she dislikes Misaki because Misaki’s good work makes her look bad. However, she does not mind that Misaki does the more difficult work in the café, so she holds nothing against her. Honoka does not have a full-time job and makes a living from part time work. She can become somewhat maniacal about getting in character for her job and dislikes how Misaki continues to work at a maid café despite not enjoying the nature of the job.

Erika
A college student working at Café Latte. She notes that Misaki is strong and picks up work quickly, though she finds that it does not feel as though Misaki is younger than her. She has a tendency to eavesdrop and is described as having a “voice fetish.”

Subaru
An employee at Café Latte. Like Honoka, she does not have a full-time job and makes a living from part-time work. She considers Misaki to be hard working.

Sayu, Gon-chan
Two other employees at Café Latte. Sayu is 18 and Gon-chan is 20 years old. They do not appear often.

Aoi Hyoudou
Satsuki’s nephew, the son of Satsuki's older brother, a junior high school student who enjoys dressing like a girl. His androgynous features allow him to pass off as a girl and his female persona is well-known as a cute internet idol. Aoi enjoys toying with the feelings of men, but is eventually exposed as a boy to Misaki by Usui. He have feelings for Misaki even though he didn't realize it.

Nagisa Hyoudou
Satsuki’s younger sister and Aoi's aunt, Nagisa is the manager of a beach house known as “Ocean House.” She asks for Satsuki and her employees to come and work at her beach house during the summer since her shop is not as popular as she would like. Nagisa is somewhat tough on Aoi for trying to dress like a girl because her older brother sent Aoi to her beach house to become more masculine.

Miyabigaoka High School

Tora Igarashi
The Student Council President at Miyabigaoka High School, he initially appears as a gentleman who marvels at Misaki and the changes she has brought to Seika High, offering her a chance to come to Miyabigaoka with an exceptional loan. He is quickly revealed to be a lecherous young man who has become bored with the women surrounding him, who are easily submissive because of his wealth. He enjoys causing drama around him.

Kanade Maki
The Vice President of the Student Council at Miyabigaoka High, he and Igarashi attempt to buy out Café Latte and change it into a butler café. Misaki, Takumi, and the Café Latte staff are able to prevent him from realizing his plans through a competition.

Hirofumi Koganei
A bespectacled student at Miyabigaoka High School who looks down upon Seika students. After insulting two students for taking an interest in chess, they hit him and Misaki forces them to go with her to apologize to him. When she discovers the reason why they attacked Koganei, she demands that Koganei apologize them her students as well. He agrees, only on the condition that they defeat him in chess, which Usui does with little trouble. Koganei is ranked fourth in the nation as a chess player. He was originally intended to be the president of Miyabigaoka High School Council by the author, but rejected by the editor. [2]